Creation of Discrete 1D Microstructures: Directional Dissociation from the Ends of a Metastable Supramolecular Polymer,ChemPlusChem

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Creation of Discrete 1D Microstructures: Directional Dissociation from the Ends of a Metastable Supramolecular Polymer
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-10-29 , DOI: 10.1002/cplu.201900611
Chisako Kanzaki ₁ , Takuya Nakadozono ₁ , Munenori Numata ₁

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The cover feature shows how an oligo(p‐phenylenevinylene) (OPV)‐based amphiphilic molecule bearing amide groups undergoes temporary self‐assembly in laminar flow. Spontaneous co‐assembly of two kinds of OPV monomers under kinetic conditions leads to the periodic insertion of different interactions into the resulting metastable nanofibers. The directional dissociation of the fibers can be terminated at these positions to produce discrete microstructures that can act as building blocks for further assembly. More details are given in the Communication by M. Numata and co‐workers (DOI: 10.1002/cplu.201900463).

中文翻译：

离散一维微结构的创建：从亚稳态超分子聚合物的末端定向解离。

封面功能显示了带有酰胺基团的基于寡聚（对-亚苯基亚乙烯基）（OPV）的两亲分子如何在层流中进行临时自组装。两种OPV单体在动力学条件下的自发共组装会导致不同的相互作用周期性地插入到最终的亚稳纳米纤维中。纤维的定向解离可以在这些位置终止，以产生离散的微结构，该微结构可以用作进一步组装的基础。M.Numata及其同事的来信（DOI：10.1002 / cplu.201900463）中提供了更多详细信息。

更新日期：2019-10-29

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