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Experimental pressure versus temperature isochoric – isoplethic curves for n-pentane – dimethyl ether, n-pentane – dimethyl ether – polybutadiene and n-pentane – dimethyl ether – polybutadiene– hydrogen at high pressures
The Journal of Supercritical Fluids ( IF 3.4 ) Pub Date : 2019-10-23 , DOI: 10.1016/j.supflu.2019.104660
Matías Menossi , Juan M. Milanesio , Andrés Ciolino , Séverine Camy , Marcelo S. Zabaloy

Loci of isochoric - isoplethic experimental phase equilibrium data, were determined for the binary mixture dimethyl ether (DME) + n-pentane (C5); the ternary mixture: DME + C5 + polybutadiene (PB); and the quaternary mixture DME + C5 + PB + hydrogen (H2). Binary experiments were performed at varying overall density (ρ) and varying quantity of C5. Ternary experiments were performed at varying ρ and varying relative quantities of each light solvent. In the case of quaternary mixtures, the mass fraction of polymer was kept constant, and the amount of H2 and ρ were varied. The experimental data obtained for binary and ternary mixtures were correlated using the Perturbed-Chain Statistical Associating Fluid Theory (PC-SAFT) equation of state (EoS).



中文翻译:

在高压下戊烷-二甲醚,戊烷-二甲醚-聚丁二烯和戊烷-二甲醚-聚丁二烯-氢气的实验压力与温度的等静压-等体积曲线

测定了二元混合物二甲醚(DME)+戊烷(C 5)的等容-等容实验相平衡数据 。三元混合物:DME + C 5  +聚丁二烯(PB);四元混合物DME + C 5  + PB +氢(H 2)。在变化的总密度(ρ)和变化的C 5量下进行了二元实验。在每种光溶剂的ρ和相对量变化的情况下进行了三元实验。在四元混合物的情况下,聚合物的质量分数保持恒定,并且H 2的量和ρ是变化的。使用扰动链统计缔合流体理论(PC-SAFT)状态方程(EoS)对二元和三元混合物获得的实验数据进行关联。

更新日期:2019-10-23
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