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Acidic H2O2 treatment of LaCoO3 towards highly dispersed Co3O4 nanoparticles with excellent catalytic performance for C3H8 combustion
Catalysis Communications ( IF 3.4 ) Pub Date : 2019-10-24 , DOI: 10.1016/j.catcom.2019.105830
Junxuan Yao , Huaiqian Lu , Bo Hou , Litao Jia , Yong Xiao , Debao Li

The acidic H2O2 solution employed in the treatment of LaCoO3 resulted in an improved porosity and the formation of Co3O4 nanoparticles highly dispersed on the surface of LaCoO3. The resulting solid exhibited superior catalytic activity towards propane combustion with T50 as low as 254 °C, high stability with time on stream (up to 48 h) and excellent water tolerance. This catalytic behavior was associated with the increase in the concentration of oxygen vacancies in the formed perovskite solid support.



中文翻译:

LaCoO 3的酸性H 2 O 2处理对高度分散的Co 3 O 4纳米粒子具有出色的催化性能,可促进C 3 H 8燃烧

用于处理LaCoO 3的酸性H 2 O 2溶液可改善孔隙率,并形成高度分散在LaCoO 3表面的Co 3 O 4纳米颗粒。所得固体在低至254°C的T 50下对丙烷燃烧表现出优异的催化活性,在运行时间(长达48小时)中具有很高的稳定性,并且具有出色的耐水性。这种催化行为与所形成的钙钛矿固体载体中氧空位浓度的增加有关。

更新日期:2019-10-24
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