Circularly polarised luminescence from planar-chiral Phanephos/Tb(iii)(hfa)3 hybrid luminophores.,Photochemical & Photobiological Sciences

当前位置： X-MOL 学术 › Photochem. Photobiol. Sci. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Circularly polarised luminescence from planar-chiral Phanephos/Tb(iii)(hfa)3 hybrid luminophores.
Photochemical & Photobiological Sciences ( IF 2.7 ) Pub Date : 2019-11-05 , DOI: 10.1039/c9pp00296k
Ayano Taniguchi ₁ , Nobuyuki Hara ₁ , Motohiro Shizuma ₂ , Nobuo Tajima ₃ , Michiya Fujiki ₄ , Yoshitane Imai ₁

Affiliation

Planar-chiral Phanephos, containing the coordinatable P(iii), formed P(iii)/Tb(iii)(hfa)3 hybrid luminophores that successfully emitted characteristic circularly polarised luminescence (CPL) due to 5D4→7F5 transitions in solution. On the other hand, BINAP, containing P(iii)[double bond, length as m-dash]O as axially chiral ligand, exhibited no detectable CPL with Tb(iii)(hfa)3.

中文翻译：

平面手性Phanephos / Tb（iii）（hfa）3杂化发光体的圆偏振发光。

包含可协调的P（iii）的平面-手性Phanephos形成P（iii）/ Tb（iii）（hfa）3杂化发光体，由于溶液中的5D4→7F5跃迁而成功地发射了特征性的圆偏振发光（CPL）。另一方面，含有P（iii）[双键，长度为m-虚线] O作为轴向手性配体的BINAP没有显示出可检测到的具有Tb（iii）（hfa）3的CPL。

更新日期：2019-12-04

点击分享查看原文

点击收藏

阅读更多本刊最新论文本刊介绍/投稿指南11