Anti-Markovnikov hydroazidation of unactivated alkenes using ABX2014;N₃ as an initiator has been developed at room temperature, wherein hydrogen azide (HN₃) acts as both hydrogen and azidating agent. Notably, the HN₃ reagent was generated from azidotrimethylsilane (TMSN₃) and acetic acid in situ. The reaction itself displays broad substrate scope, good yields and excellent regioselectivities.

中文翻译：

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碘（III）试剂（ABX-N3诱导的未活化烯烃的分子间反马尔科夫尼科夫加氢叠氮

在室温下开发了使用ABX2014; N ₃作为引发剂的未活化烯烃的反马尔科夫尼科夫加氢叠氮反应，其中叠氮化氢（HN ₃）同时充当氢和叠氮化剂。值得注意的是，HN ₃试剂是由叠氮基_三甲基硅烷（TMSN ₃）和乙酸原位生成的。该反应本身显示出宽的底物范围，良好的产率和优异的区域选择性。