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A Family of Heterocyclic Naphthalene Diimide (NDI) Analogues: Comparing Parent Isoquinoline Diimides and Phthalazine Diimides with NDI.
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-10-01 , DOI: 10.1002/cplu.201900596
Alberto Insuasty 1 , Serena Carrara 2 , Linjing Tang 3 , Craig Forsyth 4 , Conor F Hogan 2 , Christopher R McNeill 3 , Steven J Langford 1
Affiliation  

Parent isoquinoline diimide (IQDI) and phthalazine diimide (PTDI), as two new heterocyclic analogues of naphthalene diimides (NDIs), have been synthesized through an oxidative strategy in 35-79 % yield. X-ray crystallography has been used to support the formation of IQDI, which also show fluorescence quantum yields of 3.5 %. The electrochemical and electrical properties of these molecules have been studied. The electrochemical results show an interesting trend in first reduction potential PTDI

中文翻译:

杂环萘二酰亚胺(NDI)类似物系列:比较母体异喹啉二酰亚胺和邻苯二甲酰二嗪与NDI。

母体异喹啉二酰亚胺(IQDI)和邻苯二甲酰二酰亚胺(PTDI)作为萘二酰亚胺(NDI)的两个新杂环类似物,已通过氧化策略合成,产率为35-79%。X射线晶体学已用于支持IQDI的形成,IQDI也显示出3.5%的荧光量子产率。已经研究了这些分子的电化学和电学性质。电化学结果显示出首次还原电位PTDI的有趣趋势
更新日期:2019-10-30
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