This review describes the recent advances in ruthenium–nitrosoarene chemistry. The preparations of Ru–nitrosoarene complexes by (1) intermolecular nitrosonium insertion into Ru–aryl bonds, and (2) Ru-induced symmetric or asymmetric cleavage of benzofuroxan, are discussed. The exploration of the redox non-innocence of the coordinated nitrosoarene, dinitrosoarene and structurally related ligands via structural, spectroscopic, electrochemical and computational studies are presented.

中文翻译：

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钌-亚硝基芳烃化学的最新进展：非常规合成策略，新的配体设计以及对配体氧化还原无毒化的探索

这篇综述描述了钌-亚硝基芳烃化学的最新进展。讨论了通过以下方法制备Ru-亚硝基芳烃配合物：（1）将分子间的硝基son插入Ru-芳基键中，以及（2）Ru诱导的对苯并呋喃的对称或不对称裂解。提出了通过结构，光谱，电化学和计算研究探索配位的亚硝基芳烃，二亚硝基芳烃和与结构相关的配体的氧化还原非纯的方法。