1,2,5‐Oxadiazole‐Based High‐Energy‐Density Materials: Synthesis and Performance,ChemPlusChem

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1,2,5‐Oxadiazole‐Based High‐Energy‐Density Materials: Synthesis and Performance
ChemPlusChem ( IF 3.0 ) Pub Date : 2019-11-08 , DOI: 10.1002/cplu.201900542
Leonid L. Fershtat ₁ , Nina N. Makhova ₁

Affiliation

This Review covers the synthesis and performance of the most promising 1,2,5‐oxadiazole‐based high‐energy density materials (HEDMs). These materials comprise a 1,2,5‐oxadiazole subunit as a key structural motif linked to various acyclic explosophoric groups or to nitrogen‐rich and nitrogen‐oxygen azoles: 1,2,4‐triazole, tetrazole, 1,2,4‐ and 1,3,4‐oxadiazoles. Energetic alliances of two and more 1,2,5‐oxadiazole rings linked directly or through heteroatom spacers are also presented. Particular attention is devoted to the installation of different explosophores: nitro, nitramino, azo, azoxy, dinitromethyl, trinitroethyl moieties and their combination. Promising environmentally benign energetic materials with high detonation velocity and pressure, and outstanding insensitivity are summarized. Overall, the presented materials may be considered as next‐generation high‐performance energetic materials that are superior to commonly used traditional explosives (TNT, PETN, RDX, HMX).

中文翻译：

1,2,5-基于恶二唑的高能量密度材料：合成与性能

这篇综述涵盖了最有前途的基于1,2,5-恶二唑的高能量密度材料（HEDM）的合成和性能。这些材料包含一个1,2,5-恶二唑亚基，作为与各种无环发稠基团或与富氮和氮氧唑连接的关键结构基序：1,2,4-三唑，四唑，1,2,4-和1,3,4-恶二唑还介绍了两个或多个直接或通过杂原子间隔基连接的1,2,5-恶二唑环的能量联盟。特别注意的是安装不同的发爆剂：硝基，硝基氨基，偶氮，甲氧基，二硝基甲基，三硝基乙基部分及其组合。总结了具有良好爆轰速度和爆破压力的环境有益的高能材料，并具有出色的不敏感性。全面的，

更新日期：2019-11-08

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