Hazardous and toxic chemical species are omnipresent and predominantly discharged by anthropogenic activities and posing a serious threat to the environment, humane health and aquatic life. Thus, their detection remains a serious task from both environmental and biological standpoint, especially in the vapor, gas or liquid phase, are of extreme importance. In recent times, extremely porous luminescent metal-organic frameworks (LMOFs), with abundant functional groups, high surface area, excellent chemical stability and structural tunability, have emerged into an attractive area of sensory materials and device fabrication for the detection of various forms of hazardous pollutants. Herein, we present the recent progress on LMOFs and LMOFs based composite materials as sensing probes for the efficient detection of the toxicants in a variety of sensing domains, including ionic species, volatile organic compounds, explosives, biomolecules, environmental toxins, and many others. This comprehensive review summarizes the topical developments in the field of luminescent MOF and MOF-based thin film/crystals sensory materials.

危险和有毒的化学物质无处不在，主要通过人为活动排放，对环境，人类健康和水生生物构成严重威胁。因此，从环境和生物学的角度来看，对它们的检测仍然是一项艰巨的任务，特别是在气相，气相或液相中，具有极其重要的意义。近年来，具有丰富的官能团，高表面积，出色的化学稳定性和结构可调性的极多孔发光金属有机骨架（LMOF）成为传感材料和器件制造领域中的一种引人注目的领域，可用于检测各种形式的金属。有害污染物。在此处，我们介绍了基于LMOF和基于LMOF的复合材料作为传感探针的最新进展，这些传感探针可有效检测各种传感领域中的有毒物质，包括离子物种，挥发性有机化合物，炸药，生物分子，环境毒素等。这份全面的综述总结了发光MOF和基于MOF的薄膜/晶体感官材料领域的主题发展。