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Activation of tetrafluoropropenes by rhodium(i) germyl and silyl complexes.
Faraday Discussions ( IF 3.797 ) Pub Date : 2019-12-02 , DOI: 10.1039/c9fd00059c
Maria Talavera,Robert Müller,Theresia Ahrens,Cortney N von Hahmann,Beatrice Braun-Cula,Martin Kaupp,Thomas Braun

The reaction of the rhodium(i) complexes [Rh(E)(PEt3)3] (E = GePh3 (1), Si(OEt)3 (5)) with HFO-1234yf (2,3,3,3-tetrafluoropropene) afforded [Rh(F)(PEt3)3] (2) and the functionalized olefins Z-CF3CH[double bond, length as m-dash]CH(E) (E = GePh3 (4a), Si(OEt)3 (7)). Conceivable reaction pathways were assessed using DFT calculations. Reactions of [Rh(E)(PEt3)3] with HFO-1234ze (E-1,3,3,3-tetrafluoropropene) yielded the rhodium fluorido complex 2 and [Rh{(E)-CH[double bond, length as m-dash]CH(CF3)}(PEt3)3] (9) via two different reaction pathways. Using complexes 1 and 5 as catalysts, functionalized building blocks were obtained.
更新日期:2019-12-04

 

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