Metal-organic frameworks (MOFs) are a class of porous materials with unprecedented chemical and structural tunability. Their synthetic versatility, long-range order, and rich host–guest chemistry make MOFs ideal platforms for identifying design features for advanced functional materials. This review addresses synthetic approaches to control MOF attributes for realizing material properties such as charge conductivity, stability, surface area, and flexibility. Along with an updated account on MOFs employed in batteries and supercapacitors, new directions are outlined for advancing MOF research in emergent technologies such as solid-state electrolytes and battery operation in extreme environments.

金属有机框架（MOF）是一类具有前所未有的化学和结构可调性的多孔材料。它们的合成多功能性，远距离有序性和丰富的来宾客体化学特性使MOF成为识别高级功能材料设计特征的理想平台。这篇综述提出了控制MOF属性的合成方法，以实现材料特性，例如电荷电导率，稳定性，表面积和柔韧性。连同有关电池和超级电容器中使用的MOF的最新资料，概述了推动MOF研究新兴技术（例如固态电解质和极端环境下的电池操作）的新方向。