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Peanut shell as a green biomolecule support for anchoring Cu2O: a biocatalyst for green synthesis of 1,2,3-triazoles under ultrasonic irradiation
BMC Chemistry ( IF 4.3 ) Pub Date : 2019-07-24 , DOI: 10.1186/s13065-019-0612-9
Zahra Dolatkhah 1 , Abolfazl Mohammadkhani 2 , Shahrzad Javanshir 1 , Ayoob Bazgir 2
Affiliation  

Cu2O supported on peanut shell (Cu2O@PS) was prepared by the reaction of copper acetate and peanut shell powder as a naturally available biopolymer support. The prepared catalyst was used as an efficient and reusable heterogeneous catalyst in the click reaction of benzyl halide or phenacyl bromides, acetylenes and sodium azide for the synthesis of potentially biologically active 1,2,3-triazoles under ultrasonic irradiation in EtOH-H2O as green solvent.

中文翻译:

花生壳作为锚定Cu2O的绿色生物分子载体:超声辐射下绿色合成1,2,3-三唑的生物催化剂

花生壳负载Cu2O(Cu2O@PS)是通过醋酸铜与花生壳粉反应制备的,作为天然可用的生物聚合物载体。所制备的催化剂作为一种高效且可重复使用的多相催化剂,用于卤化苄或苯甲酰溴、乙炔和叠氮化钠的点击反应,在超声波照射下,EtOH-H2O中绿色合成具有潜在生物活性的1,2,3-三唑。溶剂。
更新日期:2019-07-24
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