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Novel CS2 storage materials from ion-like liquids for one-step synthesis of active nano-metal sulfides in the photocatalytic reduction of CO2
Journal of Cleaner Production ( IF 11.1 ) Pub Date : 2019-07-18 , DOI: 10.1016/j.jclepro.2019.117710
Xiaoqing Yue , Qiang Li , Bin Li , Long Zhao , Yu Wu , Tingyu Yang , Kai Liu , Jianbin Zhang , Ning Zhu

In the past two decades, a large number of organic sulfur compounds such as CS2 have been released into the atmosphere, which has caused some impacts on the environment. At present, most of the industrial treatment methods of CS2 have a series of problems, such as high energy consumption, the use of catalysts and additional treatment of by-products, which are not advisable from the economic point of view. Therefore, in this work, a method of efficient and rapid storage of CS2 by EDAs + EGs ionic liquid systems at room temperature and pressure without catalyst were proposed. At the same time, the change trend of temperature and conductivity of EDAs + EGs systems during CS2 storage were determined. Secondly, in order to realize the resource utilization of CS2SM, the mechanism of EDAs + EGs system storage CS2 and the properties of CS2SM were further studied by NMR, FTIR, XPS, XRD and other modern spectral techniques. The results showed that white precipitate with high melting point (127–224 °C) and high thermal stability were formed after CS2 is stored in the systems. These white precipitates had a similar chemical structure ([+H3NR1NH3+ SC(=S)OR2(R3)O(S = )CS]n), which were named as carbon disulfide storage material (CS2SM). Furthermore, CS2SMs were used as raw materials to one-step synthesize nano-metal sulfides (MSs) with excellent photocatalytic activity in the reduction of CO2. This provides a new method for the rapid storage and utilization of CS2, and it also has important practical significance for reducing CS2 emissions and realizing effective utilization of CS2. This efficient, green and universally applicable CS2 capture method is of great significance to reduce its hazards and obtain valuable chemicals.



中文翻译:

新型离子态CS 2存储材料,用于一步法合成活性纳米金属硫化物,光催化还原CO 2

在过去的二十年中,大量的有机硫化合物(例如CS 2)已经释放到大气中,这对环境产生了一些影响。当前,CS 2的大多数工业处理方法具有一系列问题,例如高能耗,催化剂的使用以及副产物的额外处理,从经济的角度来看,这是不建议的。因此,在这项工作中,提出了一种在室温和压力下通过EDAs + EGs离子液体系统在没有催化剂的情况下有效快速存储CS 2的方法。同时,CS 2期间EDAs + EGs系统的温度和电导率的变化趋势确定存储。其次,为了实现CS 2 SM的资源利用,利用NMR,FTIR,XPS,XRD等现代光谱技术对EDAs + EGs系统CS 2的存储机理以及CS 2 SM的性质进行了研究。结果表明,将CS 2储存在系统中后,形成了具有高熔点(127–224°C)和高热稳定性的白色沉淀物。这些白色沉淀也有类似的化学结构([ + ħ 3 NR 1 NH 3 + - SC(= S)OR 2(R 3)O(S =)CS - ] Ñ),它们被称为二硫化碳存储材料(CS 2 SM)。此外,以CS 2 SM为原料,一步法合成了具有优异的光催化活性的纳米金属硫化物(MSs),可还原CO 2。这为CS 2的快速储存和利用提供了一种新的方法,对于减少CS 2的排放和实现CS 2的有效利用也具有重要的现实意义。这种高效,绿色且普遍适用的CS 2捕获方法对于减少其危害并获得有价值的化学物质具有重要意义。

更新日期:2019-07-18
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