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Porous polymers and metallic nanoparticles: A hybrid wedding as a robust method toward efficient supported catalytic systems
Progress in Polymer Science ( IF 27.1 ) Pub Date : 2019-05-28 , DOI: 10.1016/j.progpolymsci.2019.05.003
Romain Poupart , Daniel Grande , Benjamin Carbonnier , Benjamin Le Droumaguet

Nanoparticles have been the subject of numerous studies in recent years, due to their unique intrinsic properties. In particular, their development in heterogeneous catalysis is growing. Nevertheless, they display drawbacks, including notably the question of their recyclability. In order to avoid tedious filtration steps, metallic nanoparticles may be advantageously supported on miscellaneous porous materials. Polymer materials may be envisaged as versatile and effective supports, due to their low production cost and easy functionalization. This review will first focus on different types of porous polymers developed in view of their further use as catalytic supports. Then, a brief description of the nanoparticles synthesis will be addressed, before a presentation of typical examples reported in the literature on metallic nanoparticles immobilized on porous polymers meant for use as heterogeneous supported catalysis.



中文翻译:

多孔聚合物和金属纳米颗粒:混合婚礼作为一种有效方法,可有效催化负载的催化体系

纳米颗粒由于其独特的固有性质,近年来已成为众多研究的主题。特别地,它们在非均相催化中的发展正在增长。然而,它们显示出缺点,特别是其可回收性问题。为了避免繁琐的过滤步骤,可以将金属纳米颗粒有利地负载在各种多孔材料上。聚合物材料由于其低的生产成本和容易的功能化而可以被设想为通用且有效的载体。鉴于其进一步用作催化载体,本综述将首先关注开发的不同类型的多孔聚合物。然后,将对纳米粒子的合成进行简要说明,

更新日期:2019-05-28
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