Mitigating corrosion remains a daunting challenge due to localized, nanoscale corrosion events that are poorly understood but are known to cause unpredictable variations in material longevity. Here, the most recent advances in liquid-cell transmission electron microscopy were employed to capture the advent of localized aqueous corrosion in carbon steel at the nanoscale and in real time. Localized corrosion initiated at a triple junction formed by a solitary cementite grain and two ferrite grains and then continued at the electrochemically-active boundary between these two phases. With this analysis, we identified facetted pitting at the phase boundary, uniform corrosion rates from the steel surface, and data that suggest that a re-initiating galvanic corrosion mechanism is possible in this environment. These observations represent an important step toward atomically defining nanoscale corrosion mechanisms, enabling the informed development of next-generation inhibition technologies and the improvement of corrosion predictive models.

缓解腐蚀仍然是一个艰巨的挑战，这是由于人们对局部纳米级腐蚀事件的了解甚少，但是众所周知，这种腐蚀事件会导致材料寿命的不可预测的变化。在这里，采用了液体细胞透射电子显微镜的最新进展，以纳米级实时捕获碳钢中局部水腐蚀的出现。局部腐蚀在由孤渗碳体晶粒和两个铁素体晶粒形成的三重结处开始，然后在这两个相之间的电化学活性边界处继续。通过此分析，我们确定了相边界处的刻面点蚀，钢表面的均匀腐蚀速率，以及表明在这种环境下可能重新引发电化腐蚀机理的数据。