In this work, the catalytic activity of ruthenium II and III complexes containing chloride, pyridine, phosphine and CO ligands was investigated in the hydroformylation – hydrogenation and hydroformylation – acetalization reactions. The complexes mer-[RuCl₃(dppb)(H₂O)](1), mer-[RuCl₃(dppb)(4-Vpy)](2), mer-[RuCl₃(dppb)(4-tBupy)](3), mer-[RuCl₃(dppb)(py)](4), mer-[RuCl₃(dppb)(4-Phpy)](5), mer-[RuCl₃(dppb)(4-Mepy)](6), cis-[RuCl₂(CO)₂(dppb)](7), trans-[RuCl₂(CO)₂(dppb)](8), RuCl₃·xH₂O(9), [RuCl₂(PPh₃)₃](10) and [RuCl₂(PPh₃)₂(dppb)](11) were used as supplied or synthesized as previously described in the literature {Where PPh₃ = triphenylphosphine, dppb = 1,4-bis(diphenylphosphino)butane, py = pyridine, 4-Mepy = 4-methylpyridine, 4-Vpy = 4-vinylpyridine, 4-tBupy = 4-tert-butylpyridine and 4-Phpy = 4-phenylpyridine}. These complexes were used as a pre-catalysts in a hydroformylation catalytic system to produce CC, CO and CO bonds, where 1-decene resulted in a formation of respective alcohol and dimethyl acetals. Several reactions were performed in order to find the best reaction conditions presenting the best conversion (64% after 24 h). The 1-decene was also used as a substrate in two type tandem reactions labeled as: hydroformylation – hydrogenation (HH) and hydroformylation – acetalization (HA) reactions. The relationship between Ru – catalyst/substrate was 1:100, without free ligands or additives, in a controlled temperature and pressure. All the products of catalytic reactions HH and HA were analyzed by CG-FID with good yields.

在这项工作中，在加氢甲酰化-加氢和加氢甲酰化-缩醛化反应中研究了含氯，吡啶，膦和CO配体的钌II和III配合物的催化活性。络合物可销将[RuCl ₃（DPPB）（H ₂ O）] （1） ，可销将[RuCl ₃（DPPB）（4-VPY）] （2） ，可销将[RuCl ₃（DPPB）（4-吨Bupy）] （3），mer- [RuCl ₃（dppb）（py）] （4），mer- [RuCl ₃（dppb）（4-Phpy）] （5），mer- [RuCl ₃（dppb）（4-Mepy）] （6），顺式[RuCl ₂（CO）₂（dppb）] （7），反式[RuCl ₂（CO）₂（dppb）] （8 ），RuCl ₃ ·xH ₂ O （9），[RuCl ₂（PPh ₃）₃ ] （10）和[RuCl ₂（PPh ₃）₂（dppb）] （11）的使用或合成方法如前所述。文献{凡PPh ₃ =三苯基膦，dppb = 1,4-双（二苯基膦基）丁烷，py =吡啶，4-Mepy = 4-甲基吡啶，4-Vpy = 4-乙烯基吡啶，4- t Bupy = 4-叔丁基吡啶和4-Phpy = 4-苯基吡啶}。这些配合物在加氢甲酰化催化体系中用作预催化剂，以生产C C，C O和CO键，其中1-癸烯导致分别形成醇和二甲基乙缩醛。为了找到表现出最佳转化率的最佳反应条件（24小时后为64％），进行了几次反应。1-癸烯还用作两种类型的串联反应的底物，分别标记为：加氢甲酰化–氢化（HH）和加氢甲酰化–缩醛化（HA）反应。在受控的温度和压力下，Ru-催化剂/底物之间的关系为1：100，没有游离的配体或添加剂。用CG-FID分析了催化反应HH和HA的所有产物，收率很高。