This review article aims to cover the state-of-the-art of titanosilicate catalysts for selective oxidations developed within past seven years. Many elaborated materials (e.g., layered and pillared titanosilicates, hierarchical composite materials, and others) have been prepared and thoroughly characterized; however, their catalytic properties have been usually investigated only using a single or few model substrates and compared with a benchmarking material. The main goal of this article is to summarize the novel catalysts and compare their catalytic performance with each other. The comparison is focused on epoxidation. In addition, phenol hydroxylation and sulphide oxidation are briefly covered.

中文翻译：

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先进的钛硅酸盐选择性氧化催化剂的催化性能–综述

这篇综述文章旨在介绍过去七年来开发的用于选择性氧化的钛硅酸盐催化剂的最新技术。已经准备好许多详尽的材料（例如层状和柱状钛硅酸盐，分层复合材料等）并进行了充分表征。然而，它们的催化性能通常仅使用一种或几种模型底物进行研究，并与基准材料进行比较。本文的主要目的是概述新型催化剂并相互比较它们的催化性能。比较集中在环氧化上。此外，简要介绍了酚的羟基化和硫化物的氧化。