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Synthesis of chiral carbazole-based BODIPYs showing circularly polarized luminescence†
Chemical Communications ( IF 4.3 ) Pub Date : 2019-02-15 00:00:00 , DOI: 10.1039/c9cc00894b
Chihiro Maeda 1, 2, 3, 4, 5 , Keiji Nagahata 1, 2, 3, 4, 5 , Kazuto Takaishi 1, 2, 3, 4, 5 , Tadashi Ema 1, 2, 3, 4, 5
Affiliation  

Chiral carbazole-based BODIPYs with a binaphthyl unit were synthesized via an Al-mediated reaction. Et2AlCl was found to be a convenient reagent for the reaction to give the chiral BODIPYs in high yields. It has been shown for the first time that these chiral carbazole-based BODIPYs show circularly polarized luminescence (CPL) both in solution and in the solid state.

中文翻译:

手性咔唑基BODIPY的合成显示圆偏振发光

通过铝介导的反应合成具有联萘基单元的手性咔唑基BODIPY 。发现Et 2 AlCl是用于方便地以高收率得到手性BODIPY的反应的试剂。首次显示这些手性咔唑基BODIPY在溶液和固态下均显示出圆偏振发光(CPL)。
更新日期:2019-02-15
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