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Formation of disulphide linkages restricts intramolecular motions of a fluorophore: detection of molecular oxygen in food packaging†
Chemical Communications ( IF 4.9 ) Pub Date : 2019-02-15 00:00:00 , DOI: 10.1039/c8cc10035g
Sk. Atiur Rahaman 1, 2, 3 , Dipon Kumar Mondal 1, 2, 3 , Subhajit Bandyopadhyay 1, 2, 3
Affiliation  

Reliable and easy detection of oxygen in food packaging without the aid of sophisticated instruments is highly coveted. A tetraphenylethene probe based on oxygen-mediated polymerization via the formation of disulfides causes restricted intramolecular rotation of the TPE phenyls resulting in a >100 fold enhancement of emission and thus detects O2 in food packages.

中文翻译:

二硫键的形成限制了荧光团的分子内运动:检测食品包装中的分子氧

在不借助精密仪器的情况下,可靠,简便地检测食品包装中的氧气已成为人们的垂涎。基于氧介导的聚合反应通过形成二硫化物的四苯乙烯探针导致TPE苯基的分子内旋转受到限制,从而导致发射量增加> 100倍,从而检测到食品包装中的O 2
更新日期:2019-02-15
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