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Enhanced stability of Pt/C by the atomic layer deposition of porous MOx for the decarboxylation of oleic acid
Catalysis Communications ( IF 3.4 ) Pub Date : 2019-02-12 , DOI: 10.1016/j.catcom.2019.02.003
Wenwen Lin , Hao Chen , Jing Li , Kequan Chen , Xiuyang Lu , Pingkai Ouyang , Jie Fu

Pt/C has a good performance for decarboxylation of oleic acid, but its catalytic stability needs further improvement. In this work, metal oxide films with controllable thicknesses were synthesized using atomic layer deposition to protect the Pt in the Pt/C to increase its catalytic stability. Compared to Pt/C, which showed only a 17% yield of heptadecane at the fourth catalytic cycle, the Pt/C deposited with porous Al2O3 films after high-temperature calcination showed improved catalytic stability that still obtained a 41% yield of heptadecane at the fourth catalytic cycle. These findings are important for improving the stability of noble metal–based catalysts and reducing the cost of industrial biofuel production.



中文翻译:

通过多孔MO x的原子层沉积使油酸脱羧,增强了Pt / C的稳定性

Pt / C具有良好的油酸脱羧性能,但其催化稳定性有待进一步提高。在这项工作中,使用原子层沉积法合成了厚度可控的金属氧化物膜,以保护Pt / C中的Pt以增加其催化稳定性。与在第四次催化循环中仅显示17%的庚烷收率的Pt / C相比,在高温煅烧后沉积有多孔Al 2 O 3膜的Pt / C表现出改善的催化稳定性,仍然获得41%的收率。在第四个催化循环中的庚烷。这些发现对于提高贵金属基催化剂的稳定性并降低工业生物燃料生产成本非常重要。

更新日期:2019-02-12
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