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High-performance poly(benzoxazole/benzimidazole) bio-based plastics with ultra-low dielectric constant from 3-amino-4-hydroxybenzoic acid
Polymer Degradation and Stability ( IF 5.9 ) Pub Date : 2019-02-01 , DOI: 10.1016/j.polymdegradstab.2019.01.036
Aniruddha Nag , Mohammad Asif Ali , Makoto Watanabe , Maninder Singh , Kittima Amornwachirabodee , Shunsuke Kato , Tetsu Mitsumata , Kenji Takada , Tatsuo Kaneko

High-performance bio-based plastics can make a major contribution to environmental sustainability. A series of high-performance poly(2,5-benzoxazole-co-2,5-benzimidazole)s (PBO-co-PBI) bio-based plastic films, were developed using the aromatic biomolecule 3-amino-4-hydroxybenzoic acid and the commercial product 3,4-diaminobenzoic acid. The partially bio-based PBO-co-PBI films exhibit higher thermal and mechanical performance than conventional bio-based polymers such as polyamide 11 or poly(lactic acid). The robust PBO-co-PBI films exhibit lower dielectric constants (εr) than conventional high-performance aromatic polymers, attaining the value comparable to those of polyethylene or polypropylene.



中文翻译:

3-氨基-4-羟基苯甲酸具有超低介电常数的高性能聚苯并恶唑/苯并咪唑生物基塑料

高性能生物基塑料可以为环境可持续性做出重大贡献。一系列高性能聚(2,5- benzoxazole-的-2,5-苯并咪唑)S(PBO--PBI)基于生物的塑料薄膜,使用该芳香族生物分子的3-氨基-4-羟基苯甲酸开发以及商品3,4-二氨基苯甲酸。与常规生物基聚合物(例如聚酰胺11或聚乳酸)相比,部分生物基PBO - co - PBI膜具有更高的热性能和机械性能。鲁棒PBO--PBI薄膜表现出较低的介电常数(ε - [R比传统高性能芳族聚合物),获得比得上那些聚乙烯或聚丙烯的值。

更新日期:2019-02-01
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