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Heterostructured RGO/Bi3.64Mo0.36O6.55 nanospheres: Synthesis and enhanced visible-light-driven photocatalytic activity
Journal of Molecular Catalysis A: Chemical Pub Date : 2016 , DOI: 10.1016/j.molcata.2015.10.014
Xue Lin , Siyu Yu , Zhuoyang Gao , Xiaoxu Zhang , Guangbo Che

Heterostructured RGO/Bi3.64Mo0.36O6.55 nanospheres with different weight fractions of RGO were synthesized via a simple and practical low-temperature solution-phase route by using Bi3.64Mo0.36O6.55 nanospheres as substrate materials. The as-prepared RGO/Bi3.64Mo0.36O6.55 nanoheterostructure included RGO nanoparticles assembling on the surface of Bi3.64Mo0.36O6.55 nanospheres. Comparing with pure Bi3.64Mo0.36O6.55, RGO/Bi3.64Mo0.36O6.55 hybrid photocatalysts exhibited enhanced photocatalytic activities under visible light irradiation in the decomposition of rhodamine B (RhB) solution, and the RGO/Bi3.64Mo0.36O6.55 photocatalyst with 3 wt% of RGO exhibited the highest photocatalytic activity. The enhanced performance is believed to be induced by the high specific surface area, the strong visible-light absorption originating from the sensitization of RGO, and the high efficient separation of photogenerated electron–hole pairs through RGO/Bi3.64Mo0.36O6.55 heterostructure.

中文翻译:

异质结构的RGO / Bi 3.64 Mo 0.36 O 6.55纳米球:合成和增强的可见光驱动的光催化活性

以Bi 3.64 Mo 0.36 O 6.55纳米球为基底材料,通过简单实用的低温固溶相合成了具有不同RGO重量分数的异质结构RGO / Bi 3.64 Mo 0.36 O 6.55纳米球。所制备的RGO / Bi 3.64 Mo 0.36 O 6.55纳米异质结构包括在Bi 3.64 Mo 0.36 O 6.55纳米球表面上组装的RGO纳米颗粒。与纯Bi 3.64 Mo 0.36 O 6.55相比,RGO / Bi 3.64 Mo在罗丹明B(RhB)溶液的分解中,0.36 O 6.55杂化光催化剂在可见光照射下表现出增强的光催化活性,具有3 wt%RGO的RGO / Bi 3.64 Mo 0.36 O 6.55光催化剂表现出最高的光催化活性。据信,增强的性能归因于高比表面积,源自RGO敏化的强烈可见光吸收以及通过RGO / Bi 3.64 Mo 0.36 O 6.55异质结构对光生电子-空穴对的高效分离。
更新日期:2017-01-31
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