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Carbohydrate‐Responsive Surface Adhesion Based on the Dynamic Covalent Chemistry of Phenylboronic Acid‐ and Catechol‐Containing Polymer Brushes
Angewandte Chemie International Edition ( IF 16.6 ) Pub Date : 2018-02-09 , DOI: 10.1002/anie.201711529
Sebastian Lamping 1 , Tobias Otremba 1 , Bart Jan Ravoo 1
Affiliation  

A glue, based on dynamic covalent chemistry, with a strong adhesion (2.38 kg cm−2), water resistance and carbohydrate responsive reversibility is presented. Using surface initiated atom transfer radical polymerization (SI‐ATRP), glass and silicon surfaces were coated with copolymers functionalized with phenylboronic acids and catechols. In combination with microcontact printing (μCP) these polymer brushes give access to a carbohydrate responsive “supramolecular Velcro”.

中文翻译:

基于苯硼酸和邻苯二酚的聚合物刷的动态共价化学的碳水化合物响应性表面粘附

提出了一种基于动态共价化学的胶,该胶具有强粘合力(2.38 kg cm -2),耐水性和碳水化合物响应性可逆性。使用表面引发的原子转移自由基聚合(SI‐ATRP),玻璃和硅表面涂有用苯基硼酸和邻苯二酚官能化的共聚物。与微接触印刷(μCP)结合使用时,这些聚合物刷可以访问对碳水化合物有反应的“超分子维可牢尼龙搭扣”。
更新日期:2018-02-09
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