Reactions of 5-(p-aminophenyl)-10,15,20-triphenyl porphyrin (1) with Ru₃(CO)₁₂ or M(OCOCH₃)₂ (M= Ni, Mn) afforded metalloporphyrins (4–6), respectively. 6-Deoxy-6-iodo-β-cyclodextrin (2) and mono(6-O-trifluoromethanesulfonyl) permethylated β-cyclodextrin (3) reacted with complexes 4–6 to give β-cyclodextrin bonded metal porphyrins (7–9) and permethylated β-cydodextrin bonded metal porphyrins (10–12) respectively. These new complexes were identified by MS, IR, UV-visible and ¹H NMR spectra, and elemental analysis.

中文翻译：

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β-环糊精键合金属卟啉的合成与表征

5-（对氨基苯基）-10,15,20-三苯基卟啉（1）与Ru ₃（CO）₁₂或M（OCOCH ₃）₂（M = Ni，Mn）的反应得到金属卟啉（4–6），分别。6-脱氧-6-碘-β-环糊精（2）和单（6- O-三氟甲磺酰基）过甲基化的β-环糊精（3）与配合物4-6反应生成β-环糊精键合的金属卟啉（7-9）和过甲基化的β-环糊精键合金属卟啉（10-12）。这些新的配合物通过质谱，红外光谱，紫外可见光谱和¹ H NMR光谱以及元素分析鉴定。