A microporous MOF with open metal sites and Lewis basic sites for selective CO2 capture,Dalton Transactions

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A microporous MOF with open metal sites and Lewis basic sites for selective CO2 capture
Dalton Transactions ( IF 4 ) Pub Date : 2017-10-02 00:00:00 , DOI: 10.1039/c7dt03255b
Jinjie Qian _{1,

2,

3,

4} , Qipeng Li _{4,

5,

6,

7} , Linfeng Liang _{8,

9,

10,

11,

12} , Ting-Ting Li _{4,

13,

14,

15} , Yue Hu _{1,

2,

3,

4} , Shaoming Huang _{1,

2,

3,

4}

Affiliation

College of Chemistry and Materials Engineering
Wenzhou University
Wenzhou 325035
P. R. China
College of Chemistry and Life Science
Zhaotong University
Zhaotong 657000
State Key Laboratory of Structure Chemistry
Fujian Institute of Research on the Structure of Matter
Chinese Academy of Sciences
Fuzhou
China
Research Center of Applied Solid State Chemistry
Ningbo University
Ningbo

A robust indium–organic framework (InOF-15) with open metal sites and Lewis basic sites has been successfully synthesized using a quinoline-based dicarboxylic acid. Moreover, it exhibits high IAST selective CO₂ sorption from CO₂/CH₄ and CO₂/N₂ mixtures at 273 K, which has been attributed to the coexistence of OMSs and LBSs with strong synergistic effects.

中文翻译：

具有开放金属位点和Lewis碱性位点以选择性捕获CO _2的微孔MOF

使用基于喹啉的二羧酸已成功合成了具有开放金属位点和Lewis碱性位点的坚固的铟有机骨架（InOF-15）。而且，它在273 K时从CO ₂ / CH ₄和CO ₂ / N ₂混合物中表现出很高的IAST选择性CO ₂吸附能力，这归因于OMS和LBS并存，具有很强的协同作用。

更新日期：2017-10-24

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