This study focuses on [FeFe]-hydrogenase and its metallorganic mimics in terms of electronic and photophysical properties, which can be applied to the electrochemical and/or photochemical production of molecular hydrogen. Natural [FeFe]-hydrogenase, synthetic mimics of its active site and recent progresses in hybrid-type hydrogen production, for example, inorganic-combination photoelectrochemical and photochemical hydrogen production, are reviewed.

中文翻译：

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[FeFe]-加氢酶及其有机分子模拟物—人工和生物工程学在制氢中的应用

这项研究集中于[FeFe]氢化酶及其金属有机模拟物的电子和光物理性质，可用于分子氢的电化学和/或光化学生产。审查了天然[FeFe]-加氢酶，其活性位点的合成模拟物以及混合型制氢的最新进展，例如无机组合光电化学和光化学制氢。