A BBr₃-mediated S-directed ortho C–H borylation of thiobenzamides was developed. A variety of ortho-borylated thiobenzamides were obtained in moderate to good yields with a wide functional group tolerance under simple and metal-free conditions. This transformation provided a convenient and practical route to important functionalized thiobenzamides.

中文翻译：

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硫代苯甲酰胺的无金属邻位 C–H 硼基化

开发了BBr ₃介导的硫代苯甲酰胺的 S定向邻位C-H 硼基化。在简单和无金属的条件下，以中等至良好的收率获得了多种邻硼基化硫代苯甲酰胺，并且具有广泛的官能团耐受性。这种转化为重要的官能化硫代苯甲酰胺提供了一条方便实用的途径。