Here we report a Ni-catalyzed highly regio- and stereoselective ring opening reaction of SCBs with 1,3-dienes for a straightforward and facile preparation of allylsilanes. This chemistry involves the cleavage and reconstruction of Si–C bonds and provides a versatile approach for the construction of novel longer chain allylsilanes. Operationally simple conditions, wide substrate scope, readily available materials, versatile transformation of the product, and high atom economy make this protocol attractive.

中文翻译：

---

镍(0)催化硅杂环丁烷与1,3-二烯的开环反应生成烯丙基硅烷

在这里，我们报告了镍催化的 SCB 与 1,3-二烯的高度区域和立体选择性开环反应，用于直接、简便地制备烯丙基硅烷。这种化学涉及 Si-C 键的裂解和重建，并为构建新型长链烯丙基硅烷提供了一种通用方法。操作简单的条件、广泛的底物范围、容易获得的材料、产品的多功能转化和高原子经济性使该协议具有吸引力。