Comprehensive SummaryA Pd‐catalyzed regioselective hydroesterification of alkyl terminal olefins with aryl formates is described. A wide variety of linear carboxylic esters bearing various functional groups can be obtained in good yields with high regioselectivities under mild reaction conditions by using 1,2‐DTBPMB or (p‐F‐Ph)3P as ligand. The reaction process is operationally simple and requires no handling of toxic CO or strong acid. The resulting aryl esters can be readily converted to other carboxylic acid derivatives.

中文翻译：

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Pd催化末端烷基烯烃与甲酸酯的高度区域选择性加氢酯化

综合总结描述了烷基末端烯烃与甲酸芳基酯的 Pd 催化区域选择性加氢酯化反应。通过使用 1,2-DTBPMB 或 (p-F-Ph)3P作为配体。该反应过程操作简单，不需要处理有毒的CO或强酸。所得芳基酯可以容易地转化为其他羧酸衍生物。