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Investigations on magnesium ion conducting gellan gum-based biopolymer blend electrolytes for energy storage applications
Energy & Environment ( IF 3.154 ) Pub Date : 2024-02-21 , DOI: 10.1177/0958305x241230621
Naveen C 1 , Muthuvinayagam Muthiah 1
Affiliation  

The economical and ecological polymer electrolytes are essential for energy storage devices. The key problem we are trying to resolve is how to improve ionic conductivity and safety in polymer electrolytes, which are essential for energy storage devices to operate effectively. We have prepared biopolymer blend electrolytes with different concentrations of magnesium chloride (MgCl2) by solution casting technique and the prepared electrolytes are investigated. Increase of amorphous nature of the polymer membranes is confirmed by X-ray diffraction analysis. Fourier transform infrared (FTIR) spectroscopy used to define complex formation between salt and polymers. Thermal properties of the electrolytes are confirmed by differential scanning calorimetry technique. The higher ionic conductivity of 1.04 × 10−5 S/cm has been achieved for 8 wt.% MgCl2 mixed gellan gum: polyvinyl alcohol (PVA) polymer blend at the room temperature. The present work highlights the preparation and characterization of gellan gum: PVA: MgCl2 polymer blend electrolytes with enhanced ionic conductivity and safety. The optimized polymer electrolyte is applied for energy storage devices.

中文翻译:

用于储能应用的镁离子传导结冷胶基生物聚合物混合电解质的研究

经济、生态的聚合物电解质对于储能装置至关重要。我们要解决的关键问题是如何提高聚合物电解质的离子电导率和安全性,这对于储能设备的有效运行至关重要。我们制备了具有不同浓度氯化镁(MgCl2)通过溶液浇铸技术和制备的电解质进行了研究。通过X射线衍射分析证实了聚合物膜的无定形性质的增加。傅里叶变换红外 (FTIR) 光谱用于定义盐和聚合物之间的复合物形成。电解质的热性能通过差示扫描量热技术得到证实。较高的离子电导率1.04×10−58 wt.% MgCl 已达到 S/cm2混合结冷胶:室温下聚乙烯醇(PVA)聚合物共混物。目前的工作重点介绍了结冷胶:PVA:MgCl 的制备和表征2聚合物混合电解质具有增强的离子电导率和安全性。优化后的聚合物电解质应用于储能装置。
更新日期:2024-02-21
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