The construction of effective artificial chiral light-harvesting systems (C-LHSs) is significantly important as it provides insights into the hierarchical levels of chirality evolution in natural systems. Herein, we devised pairs of chiral blue emitters, S-/R-binaphthalene dioxygen-N-octadecamidephthalimide (S-/R-BPOA), which function as donors of chirality and light absorbers. S-/R-BPOA co-assembled with enantiomers of atomically precise yellow-emitting subnanometer-scale Ag₆ clusters to fabricate C-LHSs. Within these hybrid C-LHSs, we successfully resolved enantioselective chirality/energy transfer that was dependent on the handedness of the components. This promoted the efficient circularly polarized energy transfer in chirality-compatible ensembles, resulting in a remarkable amplification of circularly polarized luminescence (CPL) in the ultrasmall silver cluster. The achieved dissymmetry factor (g_lum) reached an impressive value of 1.54 × 10⁻², and white-light CPL with chromaticity coordinates of (0.32, 0.33) was obtained. Furthermore, the customizable fluorescence and CPL in these C-LHSs bestow them with potential application possibilities in information storage and encryption.

有效的人工手性光捕获系统（ C -LHS）的构建非常重要，因为它提供了对自然系统中手性进化的层次结构的见解。在此，我们设计了成对的手性蓝色发射体，S- / R-联萘二氧-N-十八酰胺邻苯二甲酰亚胺（S- / R -BPOA），其充当手性供体和光吸收剂。S -/ R -BPOA 与原子级精确的发黄光的亚纳米级 Ag ₆簇的对映体共同组装，以制造C -LHS。在这些杂化C -LHS中，我们成功地解决了依赖于组件旋向性的对映选择性手性/能量转移。这促进了手性兼容系综中有效的圆偏振能量转移，从而导致超小银团簇中圆偏振发光（CPL）的显着放大。所获得的不对称因子（g _{lum ）达到了令人印象深刻的1.54×10} ^-2值，并且获得了色品坐标为（0.32，0.33）的白光CPL。此外，这些C -LHS中的可定制荧光和CPL赋予它们在信息存储和加密方面的潜在应用可能性。