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Microstructural Impacts on the Oxidation of Multi-Principal Element Alloys
Oxidation of Metals ( IF 2.2 ) Pub Date : 2024-02-16 , DOI: 10.1007/s11085-024-10225-2
Michael J. Pavel , Mark L. Weaver

The impacts of thermal treatment on the precipitate morphology and oxidation behavior of a dual-phase (FCC + L12) multi-principal element alloy (MPEA), Ni45Co17Cr14Fe12Al7Ti5, was studied at 1000 °C via isothermal and cyclic testing. Thermogravimetric analysis and subsequent characterization revealed that smaller precipitates had an increased capacity to form protective sub-surface oxide layers which mitigated total mass gain. The smaller-precipitate-containing samples exhibited a decrease in thickness of the primary Cr2O3 scale and parabolic growth rate. Mechanistically this behavior is believed to stem from the increased growth rate of initial Al2O3 nuclei and decreased inter-precipitate spacing which results in faster lateral diffusion and agglomeration.



中文翻译:

微观结构对多主元合金氧化的影响

研究了在 1000 ° 下热处理对双相 (FCC + L1 2 ) 多主元素合金 (MPEA) Ni 45 Co 17 Cr 14 Fe 12 Al 7 Ti 5的析出物形态和氧化行为的影响C 通过等温和循环测试。热重分析和随后的表征表明,较小的沉淀物形成保护性次表面氧化层的能力增加,从而减轻了总质量增加。含有较小沉淀物的样品表现出初生Cr 2 O 3氧化皮厚度和抛物线生长速率的减小。从机制上讲,这种行为被认为源于初始Al 2 O 3核生长速率的增加和沉淀间间距的减小,这导致更快的横向扩散和团聚。

更新日期:2024-02-17
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