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Development of Equal Proportional YSZ + Al2O3 Thermal Barrier Coating and Effect of Coating Thickness on the Corrosion Behaviour on Cast Iron Substrate
Oxidation of Metals ( IF 2.2 ) Pub Date : 2024-02-01 , DOI: 10.1007/s11085-024-10222-5
Haridasa Nayak , Shanthala Kollur , K. Prasad , Suresh Erannagari , C. Durga Prasad , N. Nagabhushana

Thermal barrier coating (TBC) degradation has been identified as a primary problem in the case of hot corrosion via Na2SO4–V2O5 deposits. In comparison with the current top coat thickness, the current research presents a novel TBC that combines equal amounts of pure alumina (Al2O3) and yttria-stabilized zirconia (YSZ) with improved resistance to heat corrosion. Using the atmospheric plasma spray (APS) process, Al2O3 and YSZ were sprayed as a bond coat on cast iron substrates using the multilayer bond coat materials Metco 410NS and Metco 452. Utilizing a cyclic method, the hot corrosion behaviour of TBC was examined at 850 °C using a corrosive salt consisting of 45 weight percent sodium sulphate (Na2SO4) and 55 weight percent vanadium pentoxide (V2O5) powders. In increments of 100 µm, the top coat thickness ranged from 100 to 300 µm. The results indicated that a 300 µm top coat thickness will result in a greater hot corrosion resistance. The disintegrate of the TBC systems is also caused by corrosive salts like Na2SO4 and V2O5, which have the ability to dissolve the stabilizers in the zirconia coating at high temperatures.



中文翻译:

等比例YSZ+Al2O3热障涂层的研制及涂层厚度对铸铁基体腐蚀行为的影响

热障涂层 (TBC) 退化已被确定为 Na 2 SO 4 –V 2 O 5沉积物热腐蚀情况下的主要问题。与目前的面漆厚度相比,当前的研究提出了一种新型TBC,它结合了等量的纯氧化铝(Al 2 O 3)和氧化钇稳定氧化锆(YSZ),具有更高的耐热腐蚀性。采用大气等离子喷涂 (APS) 工艺,使用多层粘结层材料 Metco 410NS 和 Metco 452 将 Al 2 O 3和 YSZ 作为粘结层喷涂在铸铁基材上。利用循环方法,研究了 TBC 的热腐蚀行为。使用由 45 重量%硫酸钠 (Na 2 SO 4 ) 和 55 重量%五氧化二钒 (V 2 O 5 ) 粉末组成的腐蚀性盐在 850 °C 下进行测试。以 100 µm 为增量,面漆厚度范围为 100 至 300 µm。结果表明,300 µm 的面漆厚度将带来更好的耐热腐蚀性。 TBC系统的分解也是由Na 2 SO 4和V 2 O 5等腐蚀性盐引起的,这些盐能够在高温下溶解氧化锆涂层中的稳定剂。

更新日期:2024-02-02
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