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One-pot green synthesis, study of fluorescence properties, and biological activity of pyrano[3,2-c]chromenes derivatives via mesoporous materials MgO/SBA-15
Journal of Heterocyclic Chemistry ( IF 2.4 ) Pub Date : 2023-12-27 , DOI: 10.1002/jhet.4772
Ahmed Chelihi 1 , Ridha Hassaine 1, 2 , Souad Nachat 1 , Mohammed Benabdallah 1 , Karima Bendahou 1 , Mohammed Aissaoui 3, 4 , Merzouk Saidj 5 , Ahmed Djafri 2, 5 , Leïla Boukenna 2, 6 , Abdelghani Bouchama 2 , Noureddine Choukchou‐Braham 1 , Nadia Taibi 2, 7
Affiliation  

This current work describes the preparation of MgO-SBA-15 catalysts by ultrasonic method, and it is characterized by the different analysis techniques of XRD, BET, SEM, and IRTF. In order to find out an application for this mesoporous material, MgO/SBA-15 was used as a heterogeneous catalyst in the one-pot synthesis of pyrano[3,2-c]chromenes derivatives isolated at room temperature reaction according to green chemistry criteria. To enhance these derivatives, a spectroscopic study of molecular fluorescence properties was carried out as well as an identification analysis by nuclear magnetic resonance and FTIR was used. Furthermore, biological activity experiment is also carried out, from where the obtained test results were satisfactory for AC09, AC05, and AC10 compounds and they are checked after computation by molecular modeling.

中文翻译:

介孔材料MgO/SBA-15一锅法绿色合成、吡喃并[3,2-c]色烯衍生物的荧光性质和生物活性研究

目前的工作描述了超声法制备MgO-SBA-15催化剂,并通过XRD、BET、SEM和IRTF等不同分析技术对其进行了表征。为了找到这种介孔材料的应用,根据绿色化学标准,使用MgO/SBA-15作为多相催化剂,在室温反应中一锅合成吡喃并[3,2-c]色烯衍生物。 。为了增强这些衍生物的性能,我们对分子荧光特性进行了光谱研究,并使用核磁共振和 FTIR 进行了鉴定分析。此外,还进行了生物活性实验,得到的AC09AC05AC10化合物的测试结果令人满意,并通过分子模型计算后进行了检查。
更新日期:2023-12-27
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