Using a three steps procedure a water soluble cationic bis-cyclocarbonate was prepared. Aminolysis was attempted in water but was not successful because of rapid hydrolysis of the starting cyclocarbonate in these basic conditions. Non-isocyanate polyurethanes (linear and crosslinked) were then prepared in acetonitrile with high yields. The resulting materials exhibited good thermal properties (T_deg > 230 °C) and Tg > 60 °C. The presence of the cationic moiety led to hydrophilic materials with swelling rate of 45% and a plastification effect was observed with Tg decreasing down to −28 °C. Further, considering ammonium characteristics, antibacterial properties were assessed. Surface adhesion test showed a 99,9% inhibition towards gram-positive and gram-negative bacteria for the polyurethane thermoset. Acute toxicity was evaluated on the bis-cyclocarbonate oligomer confirming its innocuity in the studied concentration range.

使用三步程序制备水溶性阳离子双环碳酸酯。尝试在水中进行氨解，但没有成功，因为起始环碳酸酯在这些碱性条件下快速水解。然后在乙腈中以高产率制备非异氰酸酯聚氨酯（线性和交联）。所得材料表现出良好的热性能（T _deg  > 230 °C）和Tg > 60 °C。阳离子部分的存在导致亲水材料的溶胀率为 45%，并且随着 Tg 降低至 -28 °C，观察到塑化效应。此外，考虑到铵的特性，评估了抗菌性能。表面附着力测试表明，聚氨酯热固性材料对革兰氏阳性菌和革兰氏阴性菌的抑制率为 99.9%。对双环碳酸酯低聚物的急性毒性进行了评估，证实其在研究浓度范围内无毒。