This study presents a highly effective FOTS-TiO₂@SiO₂ Nano fibrous membrane (NFM) with super-amphiphobic properties for oil aerosol purification. The membrane was fabricated by modifying the surface roughness of electrospun SiO₂ NFM with a uniform array of TiO₂ nanocones, followed by surface energy modification using 1H, 1H, 2H, 2H-perfluorooctyltrimethoxysilane (FOTS). The NFM exhibited exceptional contact angles towards both water (167.9°) and n-hexadecane (154.7°) as well as extremely low oil adhesion (38.7 μN). At a gas velocity of 3.2 m/min, the NFM demonstrated excellent oil aerosol separation performance, with a filtration efficiency of 99.87 % and a resistance of 10.0 kPa. The amphiphobic NFM also exhibited a good regeneration ability, with higher efficiency than SiO₂ NFM after three rounds of filtration. These results suggest that the FOTS-TiO₂@SiO₂ NFM has promising potential for cleaning oil-bearing gas.

本研究展示了一种高效的 FOTS-TiO ₂ @SiO ₂纳米纤维膜 (NFM)，具有超双疏性，可用于油气溶胶净化。该膜是通过用均匀排列的 TiO _{2改变电纺 SiO 2} NFM的表面粗糙度制成的纳米锥，然后使用 1H、1H、2H、2H-全氟辛基三甲氧基硅烷 (FOTS) 进行表面能改性。NFM 表现出对水 (167.9°) 和正十六烷 (154.7°) 的特殊接触角以及极低的油粘附力 (38.7 μN)。在 3.2 m/min 的气速下，NFM 表现出优异的油气溶胶分离性能，过滤效率为 99.87%，阻力为 10.0 kPa。双疏性NFM也表现出良好的再生能力，经过三轮过滤后，其再生效率高于SiO _{2 NFM。}这些结果表明，FOTS-TiO ₂ @SiO ₂ NFM 具有清洁含油气的巨大潜力。