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Nickelalumite, ideally NiAl4(SO4)(OH)12(H2O)3, a new-old mineral from the Kara-Tangi uranium deposit, Kyrgyzstan
Mineralogy and Petrology ( IF 1.8 ) Pub Date : 2023-06-02 , DOI: 10.1007/s00710-023-00832-3
Vladimir Yu. Karpenko , Atali A. Agakhanov , Leonid A. Pautov , Galiya K. Bekenova , Yulia A. Uvarova , Elena Sokolova , Tamara V. Dikaya , Frank C. Hawthorne

Nickelalumite, ideally NiAl4(SO4)(OH)12(H2O)3, is a newly approved mineral from the Batken region, Kyrgyzstan, where it occurs in the Kara-Tangi and Kara-Chagyr uranium deposits. It formed in a zone of hydrothermal alteration of U–V-bearing carbonaceous siliceous schists, in association with quartz, calcite, alumohydrocalcite, allophane, crandallite, kyrgyzstanite, ankinovichite and an unknown Al–OH-mineral. It occurs as aggregates of colourless to pistachio-green radiating bladed crystals from 0.05 to 0.50 mm long. It is vitreous to transparent in thin flakes, has a white streak, and shows no fluorescence under long-wave or short-wave ultraviolet light. Cleavage is perfect parallel to {001} and no parting was observed. Mohs hardness is 2, it is brittle and has a splintery fracture. The calculated mass density is 2.231 g cm–3. In transmitted plane-polarized white light, nickelalumite is non-pleochroic, biaxial, α = 1.542(2), γ = 1.533(2), β could not be measured due to the almost negligible thickness of the flakes. EPMA chemical analysis gave Al2O3 39.94, SiO2 0.17, SO3 15.20, V2O3 0.29, FeO 0.15, NiO 8.00, ZnO 6.21, (H2O)calc. 31.87, total 101.83 wt%, H2O was determined by crystal-structure analysis, and the empirical formula is as follows: (Ni0.55Zn0.39V0.02Fe0.01)Σ0.97(Al3.99Si0.01)Σ4.00 (SO4)(OH)12(H2O)3 based on 4 (Al + Si) cations. There is considerable variation in substitution of Zn, Cu, Fe and V3+ for Ni and V5+ for S6+. Nickelalumite is monoclinic, P21/n, a = 10.2567(5), b = 8.8815(4), c = 17.0989(8) Å, β = 95.548(1)°, V = 1550.3(2) Å3, Z = 4. The crystal structure of nickelalumite was refined to an R1 index of 5.66% and consists of interrupted [NiAl4(OH)12] sheets intercalated with layers of {(SO4)2(H2O)3}; nickelalumite is a member of the chalcoalumite group.



中文翻译:

镍铝矿,理想情况下为 NiAl4(SO4)(OH)12(H2O)3,一种产自吉尔吉斯斯坦卡拉-坦吉铀矿床的新旧矿物

镍铝矿,理想的情况是NiAl 4 (SO 4 )(OH) 12 (H 2 O) 3,是吉尔吉斯斯坦巴特肯地区新批准的矿物,产于卡拉-唐吉和卡拉-查吉尔铀矿床。它形成于含紫外线的碳质硅质片岩的热液蚀变带中,与石英、方解石、铝水方解石、水铝英石、铁锰铝石、吉尔吉斯斯坦石、铁钙石和一种未知的 Al-OH-矿物有关。它以无色至开心果绿色辐射状叶片晶体的聚集体形式存在,长度为 0.05 至 0.50 毫米。呈玻璃状至透明薄片状,有白色条纹,在长波或短波紫外光下无荧光。解理完全平行于{001}并且没有观察到分离。莫氏硬度为2,性脆,呈片状断裂。计算出的质量密度为2.231 g cm –3。在透射平面偏振白光下,镍铝矿是非多色性、双轴的,α = 1.542(2),γ = 1.533(2),由于薄片的厚度几乎可以忽略不计,因此无法测量β。 EPMA化学分析给出Al 2 O 3 39.94,SiO 2 0.17,SO 3 15.20,V 2 O 3 0.29,FeO 0.15,NiO 8.00,ZnO 6.21,(H 2 O)计算值。 31.87,总量101.83 wt%,通过晶体结构分析测定H 2 O,经验公式如下: (Ni 0.55 Zn 0.39 V 0.02 Fe 0.01 ) Σ0.97 (Al 3.99 Si 0.01 ) Σ4.00 (SO 4 )(OH) 12 (H 2 O) 3基于4个(Al + Si)阳离子。用Zn、Cu、Fe和V 3+代替Ni以及用V 5+代替S 6+存在相当大的变化。镍铝矿为单斜晶系,P 2 1 / n , a = 10.2567(5), b = 8.8815(4), c = 17.0989(8) Å, β = 95.548(1)°, V = 1550.3(2) Å 3 , Z = 4. 镍铝矿的晶体结构被细化至R 1指数为 5.66%,由间断的 [NiAl 4 (OH) 12 ] 片层插入 {(SO 4 ) 2 (H 2 O) 3层组成};镍铝矿是黄铜铝矿族的一员。

更新日期:2023-06-02
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