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Titanium(II) as a Fuel Atom in Energetic Materials
Inorganic Chemistry ( IF 4.3 ) Pub Date : 2023-06-02 , DOI: 10.1021/acs.inorgchem.2c04367
Alexandra M Bacon 1 , Warren Tomlinson 2 , Joseph P Hooper 2 , Michael J Zdilla 1
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The energetic content of the compounds MgTp2, FeTp2, MnTp2, and TiTp2 is measured by bomb calorimetry and compared to theoretical calculations (Tp = trispyrazoylborate). TiTp2 had the largest heat of combustion of the four compounds. Comparison of the heat of combustion of the Ti complex to those of Mg and Mn complexes suggests an effective combustion energy of TiII of between 1400 and 3000 kJ/mol, affirming the role of TiII as a strong fuel atom.

中文翻译:

钛(II)作为含能材料中的燃料原子

通过弹量热法测量化合物 MgTp 2、FeTp 2、MnTp 2和 TiTp 2的能量含量,并与理论计算值进行比较(Tp = 三吡唑基硼酸盐)。TiTp 2在四种化合物中具有最大的燃烧热。Ti络合物的燃烧热与Mg和Mn络合物的燃烧热的比较表明Ti II的有效燃烧能在1400至3000 kJ/mol之间,证实了Ti II作为强燃料原子的作用。
更新日期:2023-06-02
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