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Late-Stage Photocatalytic Fluoroalkylation of Aromatic Crown Ethers in Aqueous Media
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2023-05-26 , DOI: 10.1002/ejoc.202300478
Damian E. Yerien 1 , Jessica Groppi 2 , Al Postigo 1 , Alberto Credi 3 , Romina S. Conde 1 , Massimo Baroncini 4 , Sebastian Barata-Vallejo 5
Affiliation  

A late stage photocatalytic highly chemo- and regioselective fluoroalkylation protocol for aromatic crown ethers is reported. High yields, mild conditions, aqueous solvent, easy scalability, as well as inexpensive reagents and catalyst make this one of the few practical direct functionalization methods for this important family of macrocycles. Its wide scope is further highlighted by the post synthetic modification of mechanically interlocked molecules.

中文翻译:

水介质中芳香族冠醚的后期光催化氟烷基化

报道了芳香族冠醚的后期光催化高度化学和区域选择性氟烷基化方案。高产率、温和的条件、水性溶剂、易于扩展以及廉价的试剂和催化剂,使其成为这一重要大环家族为数不多的实用直接官能化方法之一。机械联锁分子的合成后修饰进一步凸显了其广泛的应用范围。
更新日期:2023-05-26
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