Bimetallic Al(III) Compounds as Catalysts for the Synthesis of Biodegradable Polyesters and Polycarbonates,European Journal of Organic Chemistry

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Bimetallic Al(III) Compounds as Catalysts for the Synthesis of Biodegradable Polyesters and Polycarbonates
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2023-05-24 , DOI: 10.1002/ejoc.202300371
Sourav Singha Roy ₁ , Sriparna Sarkar ₁ , P. K. Sudhadevi Antharjanam ₂ , Debashis Chakraborty ₃

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The proligands on reaction with trimethylaluminum (AlMe₃) resulted in the formation of dinuclear aluminum compounds, where the ligand moieties resemble N-alkylated salan. The aluminum compounds were active towards the ROP of rac-LA and ROCOP of CHO and CO₂ and ROCOP of epoxides (CHO, PO, tBuGE) with phthalic anhydride.

中文翻译：

双金属 Al(III) 化合物作为合成可生物降解聚酯和聚碳酸酯的催化剂

前配体与三甲基铝（AlMe ₃）反应导致形成双核铝化合物，其中配体部分类似于N-烷基化萨兰。铝化合物对外消旋-LA的ROP和CHO和CO ₂的ROCOP以及环氧化物(CHO、PO、t BuGE)与邻苯二甲酸酐的ROCOP具有活性。

更新日期：2023-05-24

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