Gas-Free Amino- and Alkoxycarbonylation of Aryl Iodides in a Bioinspired Deep Eutectic Solvent with Mo(CO)6 as a Safe CO Source,European Journal of Organic Chemistry

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Gas-Free Amino- and Alkoxycarbonylation of Aryl Iodides in a Bioinspired Deep Eutectic Solvent with Mo(CO)6 as a Safe CO Source
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2023-05-22 , DOI: 10.1002/ejoc.202300309
Francesco Messa ₁ , Andrea Nicola Paparella ₁ , Dominik Vesely ₂ , Jozef Krajčovič ₂ , Paride Papadia ₁ , Serena Perrone ₁ , Antonio Salomone ₃

Affiliation

The synergy between a nature-inspired ionic solvent and Mo(CO)₆, as a solid source of carbon monoxide, allowed to develop a Pd-catalyzed amino- and alkoxycarbonylation under mild reaction conditions and with an improved degree of sustainability.

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