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Direct Reaction – One Step Route to Synthesize Lanthanoid-iodide Formamidinates**
Chemistry - An Asian Journal ( IF 3.5 ) Pub Date : 2023-05-19 , DOI: 10.1002/asia.202300333
Zhifang Guo 1, 2 , Md Abdul Halim 2 , Victoria L Blair 1 , Glen B Deacon 1 , Peter C Junk 2
Affiliation  

This paper describes a novel and simple method – direct reaction of lanthanoid metals with equimolar amounts of iodine and a formamidine under ultrasonication as an effective, metal-based route to lanthanoid(III) diiodide formamidinates. All products have been identified by X-ray crystallography and all the trivalent complexes [Ln(Form)nI3-n] (n=1 or 2) are stable to rearrangement.

中文翻译:

直接反应 – 合成镧系元素碘化甲脒的一步路线**

本文描述了一种新颖而简单的方法——在超声波作用下,镧系金属与等摩尔量的碘和甲脒直接反应,作为一种有效的金属基路线,制备镧系元素 (III) 二碘化物甲脒酸盐。所有产物均已通过X射线晶体学鉴定,并且所有三价配合物[Ln(Form) n I 3-n ] (n=1或2)对于重排是稳定的。
更新日期:2023-05-19
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