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Facile preparation of high-performance fluorescent aramid using supercritical CO2
The Journal of Supercritical Fluids ( IF 3.4 ) Pub Date : 2023-05-10 , DOI: 10.1016/j.supflu.2023.105975
Sijia Cheng , Shengnan Li , Huanda Zheng , Bing Du , Laijiu Zheng

An ecofriendly printing strategy was developed for meta-aramid using supercritical CO2 as treatment medium. With 40% sodium carboxymethyl cellulose and 60% guar gum as original paste, violet and yellow hue were obtained for the meta-aramid fabric. After supercritical CO2 treatment, 40% printing permeability with basic violet 16% and 60% printing permeability of basic yellow 40 were reached. Moreover, the fluctuation of stiffness, the air permeability and the breaking strength of the printed meta-aramid can meet on the wearable requirement. Compared with the water-based printed aramid, washing and rubbing color fastness rated above 4 were obtained at 160 °C for basic violet 16 and at 180 °C for basic yellow 40. In addition, the printed samples presented two-photo fluorescence, and the fluorescence emission uniformly distributed throughout the entire fabric surface, which demonstrates that the printed meta-aramid can be utilized as warning materials.



中文翻译:

超临界CO2简便制备高性能荧光芳纶

开发了一种使用超临界 CO 2作为处理介质的间位芳纶环保印刷策略。以40%的羧甲基纤维素钠和60%的瓜尔豆胶为原浆,得到间位芳纶织物的紫罗兰色和黄色色相。超临界CO 2处理后,碱性紫 16% 的印花渗透率为 40%,碱性黄色 40 的印花渗透率为 60%。此外,印刷间位芳纶的刚度波动、透气性和断裂强度均能满足穿着要求。与水性印花芳纶相比,碱性紫16在160℃和碱性黄40在180℃时均获得4级以上的耐洗和耐摩擦色牢度。此外,印花样品呈现双光荧光,并且荧光发射均匀分布在整个织物表面,表明打印的间位芳纶可用作警示材料。

更新日期:2023-05-12
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