Thioether-Substituted Hexa-peri-hexabenzocoronenes,European Journal of Organic Chemistry

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Thioether-Substituted Hexa-peri-hexabenzocoronenes
European Journal of Organic Chemistry ( IF 2.5 ) Pub Date : 2023-04-27 , DOI: 10.1002/ejoc.202300299
Andreas Hirsch ₁ , René Kellner ₂ , Sven Mörsel ₃

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Hexa-peri-hexabenzocoronenes (HBCs) can be used as electron-donators in electron-transfer systems. The variation of the substitution pattern allows for the adjustment of electronic properties of the HBC core. The synthetic routes toward a series of thioether-substituted HBCs and the investigation of their electronic properties are described, as well as their reactions to the corresponding sulfones and sulfonium salts.

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