Separation and Purification Technology ( IF 8.1 ) Pub Date : 2023-03-21 , DOI: 10.1016/j.seppur.2023.123624 Chang Liu , Chuan Fu , Tingzhen Li , Panyue Zhang , Yaping Xia , Yan Wu , Qiaojuan Lan , Yurong Li , Yuexin Zhang , Jiacheng Gui
To reduce pollution and simultaneously mitigate carbon emission. Biochar samples were prepared via the pyrolysis of sludge after conditioning with K2FeO4 and cationic polyacrylamide (CPAM) or chitosan (CTS), and their CO2 capture performance was compared. The optimal preparation conditions were 600 °C and 80 mg/g dry solid (DS) for K2FeO4, 20 mg/L for CPAM, and 1 mg/g DS for CTS. The results showed that the CO2 capture capacity of the biochar with K2FeO4 (K2FeO4-B) increased from 75.69 mg/g to 81.68 mg/g compared to RSB, the CO2 capture capacity of the biochar with PF+CPAM (K2FeO4-CPAM-B) was 94.81mg/g, and the CO2 capture capacity of the biochar with PF+CTS (K2FeO4-CTS-B) was 86.56 mg/g. The CO2 capture capacity of the biochar (K2FeO4-CTS-B) was 86.56 mg/g. The main reason for this improved capacity is that the addition of K2FeO4 and CPAM enhanced chemical properties of the biochar surface (carbon content, N–H content, etc.). Additionally, the biochar conditioned with K2FeO4 and CPAM demonstrated better cyclic adsorption performance and economic efficiency than the other samples. It has the prospect of engineering application. This study provides a reference for the selection of conditioning agents for wastewater treatment plants and a new solution for sludge disposal.
中文翻译:
使用通过热解从调节污泥中提取的生物炭捕获 CO2
减少污染,同时减少碳排放。在用K 2 FeO 4和阳离子聚丙烯酰胺(CPAM)或壳聚糖(CTS)调节后,通过热解污泥制备生物炭样品,并比较了它们的CO 2捕获性能。最佳制备条件为 600 °C 和 80 mg/g 干燥固体 (DS) K 2 FeO 4、20 mg/L CPAM 和 1 mg/g DS 用于 CTS。结果表明,与RSB相比,K 2 FeO 4 (K 2 FeO 4 -B)生物炭的CO 2捕获能力从75.69 mg/g增加到81.68 mg/g,CO 2PF+CPAM(K 2 FeO 4 -CPAM-B)生物炭的捕集能力为94.81mg/g,PF+CTS(K 2 FeO 4 -CTS-B)生物炭的CO 2捕集能力为86.56毫克/克。生物炭(K 2 FeO 4 -CTS-B)的CO 2捕获能力为86.56 mg/g。这种容量提高的主要原因是添加 K 2 FeO 4和 CPAM 增强了生物炭表面的化学性质(碳含量、N-H 含量等)。此外,用 K 2 FeO 4调节的生物炭CPAM表现出比其他样品更好的循环吸附性能和经济效益。具有工程应用前景。该研究为污水处理厂调理剂的选择提供了参考,为污泥处置提供了新的解决方案。