Monitoring intramolecular proton transfer with ion mobility-mass spectrometry and in-source ion activation,Chemical Communications

当前位置： X-MOL 学术 › Chem. Commun. › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Monitoring intramolecular proton transfer with ion mobility-mass spectrometry and in-source ion activation
Chemical Communications ( IF 4.3 ) Pub Date : 2023-01-23 , DOI: 10.1039/d2cc05237g
Younes Valadbeigi ₁ , Tim Causon ₁

Affiliation

Here, we show how intramolecular proton transfer can be induced and monitored with the example of polycyclic aromatic amines using in-source ion-activation and ion mobility-mass spectrometry. Experiment and DFT calculations reveal that the protonation rate of C-atoms in aromatic rings is controlled by the energy barrier of intramolecular NH₃⁺ → C proton transfer.

中文翻译：