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Extending the Hammett correlation to mechanochemical reactions
Chemical Communications ( IF 4.3 ) Pub Date : 2023-01-20 , DOI: 10.1039/d2cc06487a
Leonarda Vugrin 1 , Maria Carta 2 , Francesco Delogu 2 , Ivan Halasz 1
Affiliation  

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical–organic chemistry could be transferable to ball milling reactions in the solid state.

中文翻译:

将 Hammett 相关性扩展到机械化学反应

使用拉曼原位监测和机械化学特异性动力学分析,我们发现在亚胺形成的模型机械化学反应中反应概率与哈米特常数之间存在相关性,表明物理-有机化学中发展的知识体系可以转移到球固态研磨反应。
更新日期:2023-01-20
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