Extending the Hammett correlation to mechanochemical reactions,Chemical Communications

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Extending the Hammett correlation to mechanochemical reactions
Chemical Communications ( IF 4.3 ) Pub Date : 2023-01-20 , DOI: 10.1039/d2cc06487a
Leonarda Vugrin ₁ , Maria Carta ₂ , Francesco Delogu ₂ , Ivan Halasz ₁

Affiliation

Using Raman in situ monitoring and mechanochemistry-specific kinetic analysis, we find a correlation between the reaction probability and the Hammett constants in a model mechanochemical reaction of imine formation, indicating that the body of knowledge developed in physical–organic chemistry could be transferable to ball milling reactions in the solid state.

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