Recent developments in visible light induced polymerization towards its application to nanopores,Chemical Communications

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Recent developments in visible light induced polymerization towards its application to nanopores
Chemical Communications ( IF 4.3 ) Pub Date : 2023-01-19 , DOI: 10.1039/d2cc06595a
Claire Förster ₁ , Annette Andrieu-Brunsen ₁

Affiliation

Visible light induced polymerizations are a strongly emerging field in recent years. Besides the often mild reaction conditions, visible light offers advantages of spatial and temporal control over chain growth, which makes visible light ideal for functionalization of surfaces and more specifically of nanoscale pores. Current challenges in nanopore functionalization include, in particular, local and highly controlled polymer functionalizations. Using spatially limited light sources such as lasers or near field modes for light-induced polymer functionalization is envisioned to allow local functionalization of nanopores and thereby improve nanoporous material performance. These light sources are usually providing visible light while classical photopolymerizations are mostly based on UV-irradiation. In this review, we highlight developments in visible light induced polymerizations and especially in visible light induced controlled polymerizations as well as their potential for nanopore functionalization. Existing examples of visible light induced polymerizations in nanopores are emphasized.

中文翻译：

可见光诱导聚合在纳米孔中的应用的最新进展

可见光诱导聚合是近年来一个新兴的领域。除了通常温和的反应条件外，可见光还具有对链增长进行空间和时间控制的优势，这使得可见光非常适合表面功能化，更具体地说是纳米级孔隙的功能化。纳米孔功能化的当前挑战包括，特别是局部和高度受控的聚合物功能化。设想使用空间受限的光源（例如激光或近场模式）进行光诱导聚合物功能化，以实现纳米孔的局部功能化，从而提高纳米多孔材料的性能。这些光源通常提供可见光，而经典的光聚合主要基于紫外线照射。在这篇评论中，我们重点介绍了可见光诱导聚合的发展，尤其是可见光诱导的受控聚合及其纳米孔功能化的潜力。强调了纳米孔中可见光诱导聚合的现有例子。

更新日期：2023-01-19

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