Superlubricity has drawn substantial attention worldwide while the energy crisis is challenging human beings. Hence, numerous endeavors are bestowed to design materials for superlubricity achievement at multiple scales. Developments in graphene-family materials, such as graphene, graphene oxide, and graphene quantum dots, initiated an epoch for atomically thin solid lubricants. Nevertheless, superlubricity achieved with graphene-family materials still needs fundamental understanding for being applied in engineering in the future. In this review, the fundamental mechanisms for superlubricity that are achieved with graphene-family materials are outlined in detail, and the problems concerning graphene superlubricity and future progress in superlubricity are proposed. This review concludes the fundamental mechanisms for graphene superlubricity and offers guidance for utilizing graphene-family materials in superlubricity systems.

在能源危机给人类带来挑战的同时，超润滑技术引起了全世界的广泛关注。因此，人们付出了许多努力来设计材料以实现多种尺度的超润滑效果。石墨烯、氧化石墨烯和石墨烯量子点等石墨烯族材料的发展开启了原子级薄固体润滑剂的时代。然而，石墨烯族材料实现的超润滑性仍需要对未来在工程中的应用有基本的了解。在这篇综述中，详细概述了石墨烯家族材料实现超润滑的基本机制，并提出了有关石墨烯超润滑的问题和超润滑的未来进展。