Minisci reaction of heteroarenes and unactivated C(sp3)–H alkanes via a photogenerated chlorine radical,Chemical Communications

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Minisci reaction of heteroarenes and unactivated C(sp3)–H alkanes via a photogenerated chlorine radical
Chemical Communications ( IF 4.3 ) Pub Date : 2023-01-13 , DOI: 10.1039/d2cc06486c
Zi-Tong Pan ₁ , Li-Miao Shen ₁ , Fentahun Wondu Dagnaw ₁ , Jian-Ji Zhong ₁ , Jing-Xin Jian ₁ , Qing-Xiao Tong ₁

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Here, an efficient Minisci reaction of heteroarenes and unactivated C(sp³)–H alkanes was achieved using an inexpensive FeCl₃ as a photocatalyst. The photogenerated chlorine radical contributed to the HAT of C–H and subsequently initiated this reaction. Surprisingly, salt water and even seawater can act as a chlorine radical source, which provided an enlightening idea for future organic synthesis methods.

中文翻译：

杂芳烃和未活化的 C(sp3)–H 烷烃通过光生氯自由基的 Minisci 反应

在这里，使用廉价的 FeCl ₃作为光催化剂实现了杂芳烃和未活化的 C(sp ^{3 )–H 烷烃的高效 Minisci 反应。}光生氯自由基有助于 C-H 的 HAT，随后引发该反应。令人惊讶的是，盐水甚至海水都可以作为氯自由基的来源，这为以后的有机合成方法提供了启发。

更新日期：2023-01-13

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